期刊
ACS CATALYSIS
卷 6, 期 3, 页码 1540-1552出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b02718
关键词
Negishi cross-coupling; zinc; palladium; nickel; copper; iron
This Perspective describes general methods for the preparation of polyfunctional zinc organometallics and their use in Negishi cross-coupling reactions. Recent advances including new ligands and palladium catalysts are described. Related Negishi cross-coupling reactions involving Ni-, Cu-, Co-, and Fe-catalyzed cross-couplings are covered. The availability of a range of zinc organometallics combined with new efficient catalysts allows for efficient cross coupling reactions with various organic electrophiles under usually mild conditions.
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