期刊
ACS CATALYSIS
卷 6, 期 2, 页码 784-787出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b02538
关键词
site-isolation; cross-linked micelle; deacetalization; nitroaldol; acid-base tandem reaction; nanoreactor
资金
- U.S. Department of Energy, Office of Basic Energy Sciences [DEFG02-03ER15459]
Shell cross-linked micelles (SCMs) containing acid sites in the shell and base sites in the core are prepared from amphiphilic poly(2-oxazoline) triblock copolymers. The materials are utilized as two-chamber nanoreactors for a prototypical acid-base bifunctional tandem deacetalization-nitroaldol reaction. The acid and base sites are localized in different regions of the micelle, allowing the two steps in the reaction sequence to largely proceed in separate compartments, akin to the compartmentalization that occurs in biological systems.
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