期刊
ACS CATALYSIS
卷 7, 期 1, 页码 833-847出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b02495
关键词
iridium; chiral dienes; catalysis; asymmetric synthesis; activation; annulation; substitution
资金
- JSPS KAKENHI [JP15H03810]
- JSPS
- Grants-in-Aid for Scientific Research [15J01245, 15H03810] Funding Source: KAKEN
Chelating chiral dienes have become steering ligands for iridium in several types of asymmetric reactions. Some effective examples realized only by use of chiral diene ligands instead of conventional ligands based on phosphine and nitrogen have appeared in the iridium-catalyzed processes. In particular, it should be noted that Ir/chiral diene catalysts allow enantioselective reactions involving C-H bond activation. In this Perspective, recent progress in asymmetric reactions catalyzed by Ir/chiral diene complexes is summarized.
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