期刊
ACS CATALYSIS
卷 6, 期 4, 页码 2496-2500出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b00346
关键词
Fe(0) particles; Fe/MFC-17; particle size effect; Fischer-Tropsch; CO hydrogenation
资金
- EU (ERC Advanced Grant) [NANOSONWINGS 2009-246763]
- INSA
- CNRS
Monodisperse Fe(0) nanoparticles with diameters between 1.8 and 9.0 nm were prepared from organometallic (Fe[N(SiMe3)(2)](2))(2) and intercalated into mesoporous MCF-17 silica. We observed high turnover frequencies of the catalytic CO hydrogenation; they increased with Fe particle size. Methane and short-chain olefin selectivities were highest for small particles, while the opposite trend applied to long-chain terminal olefins and oxygenates. The Anderson Schulz-Flory chain lengthening probabilities were found to increase with Fe particle size for both paraffins and terminal olefins. Reaction-induced sintering of the metal particles was limited and could be explained by the transformation of Fe(0) precursors into (mainly) Fe-carbides. The results cast new light on the structure sensitivity of the catalytic CO hydrogenation.
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