期刊
ACS CATALYSIS
卷 6, 期 2, 页码 1109-1112出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b02495
关键词
sulfilimines; sulfoximines; iron(III) acetylacetonate; stereospecific amination; nitrene; continuous flow process
资金
- NSERC CREATE program in Continuous Flow Science
- NSERC (Canada)
- Canada Foundation for Innovation
- Canada Research Chair Program
- Universite de Montreal
- Centre in Green Chemistry and Catalysis (CGCC)
A photochemical (UVA) continuous flow process for the amination of thioethers and sulfoxides was performed with trichloroethoxysulfonyl azide in the presence of catalytic iron(III) acetylacetonate. Aromatic and aliphatic sulfilimines and sulfoximines were produced in high yields and short reaction times. The reaction with chiral sulfoxides was stereospecific, producing enantioenriched sulfoximines in excellent yields.
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