期刊
NATURE COMMUNICATIONS
卷 7, 期 -, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/ncomms11474
关键词
-
资金
- 973 National Basic Research Program of the Ministry of Science and Technology of China [2014CB239400]
- National Natural Science Foundation of China [21573230]
Solar rechargeable flow cells (SRFCs) provide an attractive approach for in situ capture and storage of intermittent solar energy via photoelectrochemical regeneration of discharged redox species for electricity generation. However, overall SFRC performance is restricted by inefficient photoelectrochemical reactions. Here we report an efficient SRFC based on a dual-silicon photoelectrochemical cell and a quinone/bromine redox flow battery for in situ solar energy conversion and storage. Using narrow bandgap silicon for efficient photon collection and fast redox couples for rapid interface charge injection, our device shows an optimal solar-to-chemical conversion efficiency of similar to 5.9% and an overall photon-chemical-electricity energy conversion efficiency of similar to 3.2%, which, to our knowledge, outperforms previously reported SRFCs. The proposed SRFC can be self-photocharged to 0.8V and delivers a discharge capacity of 730 mAhl(-1). Our work may guide future designs for highly efficient solar rechargeable devices.
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