期刊
CHEMICAL SCIENCE
卷 7, 期 1, 页码 85-88出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc03025k
关键词
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资金
- NIHGMS [RO1 GM073932]
- MINECO
A dual photoredox and gold-catalysed cross-coupling reaction of alkynyltrimethylsilanes and aryldiazonium tetrafluoroborates is described. The reaction proceeds through visible-light mediated oxidative addition of aryldiazoniums, transmetalation of alkynyltrimethylsilanes and aryl-alkynyl reductive elimination. Exclusive selectivity for silyl-substituted alkynes is observed, with no reactivity observed for terminal alkynes.
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