期刊
CHEMICAL SCIENCE
卷 7, 期 3, 页码 2030-2036出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc03636d
关键词
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资金
- MENRT
- UPMC
- CNRS
- ANR [ANR-11-JS07-004-01]
A well-defined copper complex bearing iminosemiquinone ligands performs single electron reduction of an electrophilic CF3+ source into CF3- radicals. This redox behavior is enabled by the ligand which shuttles through two different redox states (iminosemiquinone and iminobenzoquinone) while the copper center is preserved as a Cu(II). This system was used in the trifluoromethylation of silyl enol ethers, heteroaromatics and in the hydrotrifluoromethylation of alkynes. This is the first example of cooperative redox catalysis for the controlled generation of CF3- radicals.
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