期刊
CHEMICAL SCIENCE
卷 7, 期 9, 页码 5939-5944出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc01433j
关键词
-
资金
- NSERC of Canada
- Canada Research Chair secretariat (Tier I CRC)
- National Science Foundation [CHE-1454370]
- Alfred P. Sloan Research Fellowship
- Alexander von Humboldt Foundation
- Chinese academy of Science
- CNRS
- University of Calgary
- CalMip
A dianionic tetrapodal pentadentate diborate ligand is introduced. This ligand forms a high spin neutral iron(II) complex that reacts with a variety of organoazides to yield transient Fe(III) imido radicals that are extremely potent hydrogen atom abstractors. The nature of these species is supported by full characterization of the Fe(III) amido products, kinetic studies, density functional computations and Mossbauer spectroscopy on the -C6H4-p-Bu-t substituted derivative.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据