期刊
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
卷 82, 期 -, 页码 89-99出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.trac.2016.05.016
关键词
Click polymerization; Monolithic column; Thiol-ene reaction; Ring-opening polymerization; Phase separation; Liquid chromatography
资金
- China State Key Basic Research Program Grant [2013CB911203, 2012CB910601]
- National Natural Sciences Foundation of China [21235006, 21175133, 21575141]
- Creative Research Group Project of NSFC [21321064]
- Knowledge Innovation program of DICP
In recent years, polymerizations based on click reactions (thiol-ene, thiol-yne, thiol-Michael, thiol-epoxy and amine-epoxy) have been utilized to prepare monolithic columns. These polymerization systems are easily carried out under mild conditions. Either hybrid or organic monolithic columns fabricated by click polymerization demonstrated homogeneous network structures. For separation of small molecules, the column efficiencies, such as plate height with less than 10 gm, have been greatly improved comparing with organic monolithic columns prepared with free radical polymerization. In this review, we will summarize recent progress on the preparation of monolithic columns and their chromatographic performances. (C) 2016 Elsevier B.V. All rights reserved.
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