Wet-chemical method for the metallization of a para-aramid filament yarn wound on a cylindrical dyeing package

High-performance yarns such as aramid fibers are nowadays used to reinforce composite materials due to their advantageous physico-chemical properties and their low weight. They are also resistant to heat and fire. Para-aramid filament yarns (p-AFs) wound on a cylindrical dyeing package have been silvered successfully by means of a newly developed wet-chemical filament yarn metallization process on a laboratory scale. The surface morphology of untreated and silvered p-AF was determined by means of scanning electron microscopy. The chemical structure of the surfaces (contents of carbon, oxygen, nitrogen and silver) was determined by means of energy-dispersive X-ray spectroscopy (EDX). The eliminated and newly formed groups of p-AF before and after silvering were detected by infrared spectroscopy (Fourier transformattenuated total reflectance). After metallization, the silver layer thickness, the mass-related silver content and washing and rubbing fastness were assessed. Furthermore, textile-physical examinations concerning Young's modulus, elongation at break and electrical conductivity were performed. Subsequently, the electrically conductive p-AFs were integrated in thermoset composite materials reinforced by glass fibers and para-aramid.