期刊
TETRAHEDRON LETTERS
卷 57, 期 13, 页码 1515-1517出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.02.087
关键词
beta,gamma-Unsaturated ketone chromophores; Diels-Alder cycloadditions; Norcarane derivatives; Photochemical transformations
资金
- Agencia Nacional de Investigacion e Innovacion (Uruguay)
- Comision Sectorial de Investigation Cientifica (Uruguay)
- Programa para el Desarrollo de las Ciencias Basicas (Uruguay)
- Royal Society of Chemistry (UK)
We detail a strategy for the preparation of bicyclo[4.1.0]heptanes, or norcaranes, based on Diels-Alder reactions and photochemical transformations. As the latter step of the process proceeds with unique regio and stereochemistries, the regio and stereochemical outcome of the overall sequence is dictated by the structures of the diene and dienophile and the conditions used in the initial cycloaddition reaction. This allows for the preparation of norcaranes with different substitution patterns and defined relative stereochemistries, and could be exploited in the design of complex structures bearing this bicyclic moiety. (C) 2016 Elsevier Ltd. All rights reserved.
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