期刊
TETRAHEDRON LETTERS
卷 57, 期 1, 页码 1-4出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.09.077
关键词
Metal-free; Hydroboration; Alkynes; Organoboron
资金
- Eastern Scholar
- Natural Science Foundation of Shanghai [12ZR1410500]
- NSFC [21102088, 51202138, 21174081]
- Shanghai Pujiang Program
- Key Subject of Shanghai Municipal Education Commission
Transition-metal and ligand-free method for the hydroboration of terminal alkynes with B(2)pin(2) was reported in LiOt-Bu/toluene/MeOH system under room temperature. Alkylalkynes and arylalkynes reacted efficiently with high regioselectivity. (C) 2015 Published by Elsevier Ltd.
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