期刊
TETRAHEDRON
卷 72, 期 7, 页码 959-967出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2015.12.065
关键词
Isoquinoline; Minisci reaction; C-H functionalization; Acylation; Metal-free reactions
资金
- IISc, DST, New-Delhi [SB/S1/OC-56/2013]
- RL Fine Chem
- CSIR
A method for acylation for heteroarenes under metal-free conditions has been described using NCS as an additive and TBHP as an oxidant. This method has been successfully employed in acylation of a variety of aldehyde with heteroarenes. The application of the method has been illustrated in synthesizing isoquinoline derived natural products. This strategy provides an efficient, mild and inexpensive method for acylation of heteroarenes. (C) 2015 Elsevier Ltd. All rights reserved.
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