Glutathione modified screen-printed carbon nanofiber electrode for the voltammetric determination of metal ions in natural samples

This work reports the development of a glutathione modified electrode via electrografting on a screen printed carbon nanofiber substrate (GSH-SPCNFE). GSH-SPCNFE was compared to a classical screen printed carbon electrode modified with glutathione (GSH-SPCE) for the simultaneous voltammetric determination of Cd(II) and Pb(II). Their electrochemical characterization and analytical performance suggest that SPCNFE could be a much better support for GSH immobilization. The applicability of GSH-SPCNFE for the determination of low concentration levels of Pb(II) and Cd(II) ions in environmental samples was successfully tested in a certified wastewater reference material by means of stripping voltammetry with a very high reproducibility and good trueness. (C) 2016 Elsevier B.V. All rights reserved.