Facile fabrication of Pt-Ag bimetallic nanoparticles decorated reduced graphene oxide for highly sensitive non-enzymatic hydrogen peroxide sensing

A new electrocatalyst, Pt-Ag bimetallic nanoparticles decorated reduced graphene oxide nanocomposite, was successfully synthesized by a facile, eco-friendly and controllable route. The morphological characterization of RGO/Pt-Ag NPs nanocomposite was examined by transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX) analyzer, X-ray diffraction (XRD) spectrum, and Fourier transform infrared spectrum (FT-IR), respectively. And then, the RGO/Pt-Ag NPs nanocomposite was immobilized on the surface of glassy carbon (GC) electrode to fabricate a novel and highly sensitive non enzymatic hydrogen peroxide sensor. The electrochemical behaviors of the prepared sensor were investigated by cyclic voltammetry and chronoamperometry. The sensor showed excellent performance toward H2O2 with sensitivity as high as 699.6 mu A mM(-1) cm(-2) and 402.7 A mu M-1 cm(-2), wide linear range of 0.005-1.5 mM and 1.5-7 mM, and low detection limit of 0.04 mu M (S/N=3). Moreover, the prepared hydrogen peroxide sensor was applied to in real samples with satisfactory results. These excellent results indicate that the prepared RGO/Pt-Ag NPs nanocomposite has broad application prospect in the field of sensors. (C) 2016 Elsevier B.V. All rights reserved.