期刊
SYNTHESIS-STUTTGART
卷 48, 期 19, 页码 3400-3412出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1562453
关键词
palladium; catalysis; C-H activation; allylic amination; allylic acyloxylation; but-3-enoic acid derivatives
资金
- CNRS
- UPMC
- Labex Michem
- CMST COST Action [CM1205]
Two complementary Pd-catalyzed protocols enabling the gamma-selective intermolecular allylic amination of but-3-enoic acid derivatives are reported. These transformations can be successfully achieved via either a direct Pd(II)-catalyzed protocol or by way of a one-pot Pd(II)/Pd(0)-catalyzed sequence, depending on the nature of the nitrogen nucleophile used.
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