期刊
SYNTHESIS-STUTTGART
卷 49, 期 2, 页码 252-259出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1588610
关键词
cross-coupling; dehydrogenative coupling; phenols; naphthols; biphenols; electrolysis; anodic oxidation
资金
- DFG [Wa1278/14-1]
- BMBF-EPSYLON [FKZ 13XP5016D]
The dehydrogenative cross-coupling of phenols and naphthols can be achieved by several oxidative methods. However, the key is the use of fluorinated alcohols such as 1,1,1,3,3,3-hexafluoroisopropanol. The direct application of electricity represents an alternative synthetic approach, which is superior to other oxidizers (e.g., peroxides). The method is sustainable, inherently safe, and easily scalable.
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