期刊
SYNLETT
卷 27, 期 8, 页码 1282-1286出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1561338
关键词
heterocycles; C-H functionalization; Minisci reaction; persulfates; ethers
资金
- Natural Sciences and Engineering Research Council
- University of Ottawa
- NSERC
Protocol simplification is an important aspect in the development of organic reactions such as heteroarene functionalizations. An operationally facile protocol for the direct C-H alkylation of heteroarenes with unactivated ethers has been developed. The Miniscitype radical addition process involves thermolysis of potassium persulfate, circumventing the need for transition-metal catalysts.
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