期刊
SYNLETT
卷 28, 期 5, 页码 589-592出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1588125
关键词
carboxylic acids; chemoselectivity; green chemistry; phosphorus; cyclization
资金
- Center of Excellence for Innovation in Chemistry (PERCH-CIC), Chiang Mai University, Thailand
- National Research University Project under Thailand's Office of the Higher Education Commission, Ministry of Education
A mild and convenient approach for the synthesis of 2-substituted 4H-3,1-benzoxazin-4-ones, 2-aminobenzoxazin-4-ones, and 2-amino-4H-3,1-benzothiazin-4-ones under solvent-assisted grinding is reported. In the presence of 2,4,6-trichloro-1,3,5-triazine and catalytic triphenylphosphine, cyclodehydration of N-substituted anthranilic acid derivatives proceeded rapidly within minutes at room temperature. The products were also obtained in good to excellent yields by using minimal amounts of solvent and inexpensive reagents.
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