期刊
SYNLETT
卷 27, 期 10, 页码 1443-1449出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1561619
关键词
meroterpene; hypervalent iodine; ring expansion; total synthesis; natural products; annulation
资金
- UC-Berkeley
- UC-Berkeley Hellman Fellows Fund
- Alfred P. Sloan Foundation
- NSF [CAREER] [1554544]
- NSF [DGE-1106400]
- NIH [S10-RR027172]
- Direct For Mathematical & Physical Scien [1554544] Funding Source: National Science Foundation
- Division Of Chemistry [1554544] Funding Source: National Science Foundation
Hyperforin has remained a popular and challenging synthetic target since its isolation over forty years ago. As a result, numerous synthetic strategies and ring-forming reactions have been developed to address its formidable molecular architecture. Herein we describe our contributions to this area resulting in a ten-step synthetic pathway enabled by a novel diketene annulation reaction and oxidative ring expansion strategy.
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