期刊
SYNLETT
卷 27, 期 8, 页码 1139-1144出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1561351
关键词
cyclobutanol; ring opening; free radicals; fluorination; chlorination; azidation; ketones
资金
- Soochow University
- National Natural Science Foundation of China [21402134]
- Natural Science Foundation of Jiangsu Province [BK20140306]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
Cyclobutanols serve as privileged precursors for the preparation of gamma-substituted ketones. We highlight recent advances in the radical-mediated ring-opening functionalization of cyclobutanols by fluorination, chlorination, bromination, or azidation, which open up a new vista for the synthesis of ketone derivatives. 1 Introduction 2 Silver-Catalyzed Fluorination, Chlorination, and Bromination of Cyclobutanols 3 Manganese-Catalyzed Azidation of Cyclobutanols 4 Conclusion
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