期刊
SURFACE AND INTERFACE ANALYSIS
卷 48, 期 5, 页码 293-300出版社
WILEY-BLACKWELL
DOI: 10.1002/sia.5935
关键词
graphitic nitrogen; core level shifts; oxygen reduction reactions; XPS; DFT; electrocatalysts
资金
- DOE-EERE Fuel Cell Technology Program
- National Science Foundation [DMR TG-110093]
A detailed analysis of the physiochemical nature, thermodynamic properties, and electrochemical characterization of N motifs present in self-assembled nitrogen functionalized transition metal and nitrogen doped graphene pyrolyzed materials has been conducted in this study. First principle density-functional-theory calculations were performed to assess the thermochemistry of Fe-N-x and graphitic-N defects and to predict N1s core-level-shifts. Combining this prediction with our X-ray photoelectron spectroscopy and rotating ring disk electrode experiments, we find that graphitic-N contributes significantly to hydrogen peroxide formation in oxygen reduction reactions, while materials containing nitrogen coordinated transition metal result in the complete reduction of oxygen to water. Lastly, we show how the synergy of experimental, electrochemical, and computational approaches can accelerate the accurate identification and characterization of nitrogen functionalized graphene moieties present in pyrolyzed electrocatalysts for fuel cells. Copyright (c) 2016 John Wiley & Sons, Ltd.
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