期刊
SMALL
卷 12, 期 41, 页码 5702-5709出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201601873
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资金
- National Natural Science Foundation of China [21303273, 91222201]
- 973 Program of China [2012CB821701]
- Fundamental Research Funds for the Central Universities [14lgpy21]
- Research Fund for the Doctoral Program of Higher Education [20130171120001]
- STP Project of Guangzhou [15020016]
- Natural Science Foundation of Guangdong Province [S2013040016770, S2013030013474]
A sacrificial template strategy is developed for the synthesis of yolk-shell Au@ZIF-8 nanoreactor. The Au@ZIF-8 nanoreactor possesses single-crystalline metal-organic framework (MOF) shell with intrinsic monodisperse micropores and introduced macropores. In each of the macropores, one Au NP is encapsulated to form a nanoreactor unit. The quantity of the reactor units in the MOF shell can be readily regulated. Such structure features of the Au@ZIF-8 nanoreactor facilitate the size selectivity of reactants, the accessibility of Au nanoparticles to reactants, and the mass transfer of reactants and products. As a result, the Au@ZIF-8 nanoreactor delivers excellent size selectivity, enhanced conversion, and good cycling stability when used to catalyze the aerobic oxidation of alcohols with different molecular size.
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