期刊
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B
卷 10, 期 3, 页码 451-455出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1990793116030155
关键词
high explosives; detonation mechanism; labeled-atoms method; detonation nanodiamond
This article presents a further analysis of isotopic labeling data on the mechanism of the detonation of TNT-, RDX-, and HMX-containing mixtures and on the release of free carbon from these mixtures. The distribution of carbon isotopes among the condensed explosion products and, for the first time, among the gaseous ones is considered in relation to the particle size of the mixed explosives. A sequence of main chemical reactions in the detonation wave is suggested to account for the experimental data discussed.
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