期刊
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
卷 90, 期 6, 页码 1265-1268出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S003602441606011X
关键词
electrical conductivity; dimethyl sulfoxide; copper(II) nitrate crystallohydrate; conductometry; copper plating electrolyte
Conductometry is used to investigate the electric conductivity of Cu(NO3)(2) a <... 3De(2)D solutions in dimethyl sulfoxide in the 0.01-2.82 M range of concentrations and at temperatures of 288-318 K. The limiting molar conductivity of the electrolyte and the mobility of Cu2+ and NO (3) (-) ions, the effective coefficients of diffusion of copper(II) ions and nitrate ions, and the degree and constant of electrolytic dissociation are calculated for different temperatures from the experimental results. It is established that solutions containing 0.1-0.6 M copper nitrate trihydrate in DMSO having low viscosity and high electrical conductivity can be used in electrochemical deposition.
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