期刊
RUSSIAN CHEMICAL BULLETIN
卷 65, 期 4, 页码 1013-1019出版社
SPRINGER
DOI: 10.1007/s11172-016-1405-0
关键词
polycondensation; alkoxysilane; cyclosiloxane; active medium
资金
- Russian Foundation for Basic Research [14-03-31102_mol-a]
- Grant Council of the President of the Russian Federation (State Program for Support of Young Candidates of Science) [MK-5573.2015.3]
The process of condensation of dimethyldiethoxysilane in the active medium in a presence of acetyl chloride, trifluoroacetic acid, and sulfocationites has been investigated. Their impact on the rate and selectivity of the process has been estimated. The prospects of the application of sulfocationites for the polycondensation of dimethyldiethoxysilane in anhydrous acetic acid with an 99% yield have been demonstrated.
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