期刊
RESEARCH ON CHEMICAL INTERMEDIATES
卷 42, 期 10, 页码 7447-7470出版社
SPRINGER
DOI: 10.1007/s11164-016-2546-3
关键词
Corrosion; Coordination compound; Polarization; EIS; Raman spectroscopy; XRF analysis; AFM
资金
- MESRS (Ministere de l'Enseignement Superieur et de la Recherche Scientifique)
- ATRST (Agence Thematique de Recherche Scientifique et Technologique)
A ligand, 2-((benzo[d]thiazol-2-ylthio)methyl)-1H-benzo[d]imidazole, and its zinc complex have been synthesized. The structure of these compounds have been determined by spectroscopic techniques and single crystal X-ray diffraction. The corrosion inhibition study of these compounds for steel in 0.5 M H2SO4 medium has also been investigated using potentiodynamic polarization and EIS techniques. The quantum calculations were applied to investigate the relationship between the electronic properties and the corrosion inhibition efficiency of the two benzazoles derivatives. Surface analysis (XRF) indicated that the rust layer formed on the Cu-containing steels was enriched with Cu compounds. Polarization curves revealed that both inhibitors acted as a mixed-type inhibitor.
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