期刊
RENEWABLE ENERGY
卷 87, 期 -, 页码 599-606出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.renene.2015.10.045
关键词
Ethanol organosolv pretreatment; Ethanol organosolv lignin; Combined severity factor; Liriodendron tulipifera
资金
- R&D Program for Forestry Technology by Korea Forest Service [S111314L010110]
- BK21 PLUS Program - Ministry of Education (MOE, Korea) [22A20130012223]
- National Research Foundation of Korea (NRF), (Department of Forest Sciences Seoul National University)
- Korea Forest Service [S111314L010110] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
In this study, various ethanol organosolv pretreatment factors including reaction temperature, time, and concentration of acid catalyst were evaluated for effective decomposition of lignocellulosic biomass. The different pretreatment conditions had the same combined severity factor (1.16). With an increase in reaction temperature and pH, the water-insoluble residue recovery and amount of lignin in the solid residue decreased from 52.6% to 42.4% and from 10.4% to 5.5%, respectively, whereas enzymatic digestibility increased up to 97.9%. After pretreatment, ethanol organosolv lignin (EOL) recovered from the liquid hydrolyzate was subjected to nitrobenzene oxidation, gel permeation chromatography, and supercritical ethanol treatment for evaluation of the lignin structural properties. At a higher reaction temperature and pH, the proportion of ether linkages and the polydispersity of EOL decreased from 15.7% to 10.9% and from 3.1 to 1.9, respectively, while the amount of phenolic monomers ranged from 16.7 mg/ g to 27.9 mg/g. (C) 2015 Elsevier Ltd. All rights reserved.
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