期刊
CHINESE JOURNAL OF ORGANIC CHEMISTRY
卷 35, 期 5, 页码 1146-1151出版社
SCIENCE PRESS
DOI: 10.6023/cjoc201410024
关键词
longistylin A; longistylin C; cajanotone; total synthesis
资金
- Program for New Century Excellent Talents in University [NCET-12-0656]
- Innovation Ability Promoting Program in University of Guizhou Province [2013-04]
- Natural Science Fundation for Youth in Universities of Guizhou Province [2014-300]
Natural products longistylin A, longistylin C and cajanotone belong to stilbenes family and exhibit varieties of bioactivities. Using Horner-Wadsworth-Emmons (HWE) and 1,3-sigma rearrangement reactions as key steps, longistylin A and longistylin C have been successfully synthesized in six steps from 3,5-dimethoxy benzoic acid. Besides, using Barbier and 1,3-sigma rearrangement reactions as key steps, cajanotone has been first prepared in eight steps from 3,5-dihydroxy benzoic acid.
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