期刊
PROGRESS IN ORGANIC COATINGS
卷 95, 期 -, 页码 38-45出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2016.02.008
关键词
Polypyrrole; Copper-polypyrrole; Double pulse chronoamperometry; Electrodpeosition; Polarization; Corrosion protection
资金
- Department of Science Technology, Government of India
Copper-polypyrrole (Cu-PPy) was electrochemically deposited on 304 stainless steel (SS) surfaces from various compositions of water-methanol binary mixtures containing both pyrrole monomer and metal precursor using double pulse chronoamperometry. Scanning electron microscopy (SEM) and energy dispersive analysis of X-ray (EDAX) were employed to understand the morphology and composition of the Cu-PPy coated SS. The anti-corrosive performances of the modified electrodes were investigated in 0.5 M NaCl using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. We found that after 300 h of immersion period, the Cu-PPy coating prepared from a solution containing 1:4 water to methanol volume ratio exhibited a better corrosion protection to SS than coatings prepared from other compositions. This behavior was rationalized using the low permeability and enhancement in the barrier property of the Cu-PPy coatings with increase in MeOH content. (C) 2016 Elsevier B.V. All rights reserved.
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