期刊
POLYMER INTERNATIONAL
卷 66, 期 2, 页码 187-194出版社
WILEY
DOI: 10.1002/pi.5121
关键词
cage silsesquioxanes; organic-inorganic hybrids; dendrimers; functional polymers
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [2401, 24102003]
- Grants-in-Aid for Scientific Research [24102003] Funding Source: KAKEN
This mini-review focuses on recent efforts to prepare single component element-block materials based on siloxane-based cage frameworks, a promising approach to control the sequence of organic and inorganic segments in organic-inorganic hybrids at the molecular level. Polyhedral octasilsesquioxanes, denoted (RSiO1.5)(8) or labeled T-8 cages, and octadimethylsiloxy-Q(8) cages, denoted (RSiMe2OSiO1.5)(8), are used here as siloxane-based cage frameworks. Thermoplastic optically transparent silsesquioxane materials derived from a single cage compound can be obtained with dumbbell- and star-shaped cage structures, allowing precise design of their structures for tuning properties. The siloxane-based cage core dendrimers are ideal candidates for single component element-block materials which possess three-dimensional, well-defined molecular level structures. Their rigid and cubic inorganic frameworks provide unique features for siloxane-based cage core dendrimers. These topics attract attention in both academia and industry. (c) 2016 Society of Chemical Industry
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