期刊
POLYMER CHEMISTRY
卷 7, 期 10, 页码 1857-1860出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5py02030a
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资金
- Deutsche Forschungsgemeinschaft (German Research Council, DFG)
A new approach to control the molecular weight and polymer architecture using the Passerini three-component step-growth polymerization is described. Starting from an AB-type monomer, linear homopolymers, diblock copolymers, as well as star-shaped polymers were synthesized in an efficient manner. By varying the ratio of the AB-type monomer and a suitable irreversible chain transfer agent (ICTA), different polymer architectures with specific molecular weights and high end-group fidelity were obtained.
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