This study reports the preparation by click chemistry of a novel fluorinated dendrimer bearing PVDF branches and its characterization by several analytical methods including H-1, C-13, P-31 and F-19 NMR, diffusional NMR, SEC, DLS, ATG, DSC and HRTEM. As remarkable properties, this dendritic PVDF displayed crystallinity (HRTEM highlighted crystalline disc-like zones of ca. 5 nm) and a much higher hydrophobicity than both its precursors with the water contact angle (WCA) reaching 108 degrees.
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