期刊
POLYMER
卷 107, 期 -, 页码 200-210出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2016.11.022
关键词
Carboxymethyl cellulose; Cellulose nanocrystals; Surface cationization; Interfacial interaction; Mechanical properties
资金
- National State Bureau of Forestry 948 Plan of China [2014-4-49]
- Louisiana Board of Regents [LEQSF(2016-17) ENH-TR-01, LEQSF(2015-17)-RD-B-01]
- Louisiana Board of Regents [Korea National Institute of Forest Science]
- USDA National Institute of Food and Agriculture Mclntire Stennis project [1000017]
The present work describes the development of high performance cellulose nanocrystals/carboxymethyl cellulose (CNC/CMC) films through a rational design of CNC surface chemistry. Considering the anionic surface nature of CMC, surface cationization of CNCs was performed in order to build strong interfacial bonding by electrostatic attraction and form uniform dispersion state by electrostatic repulsion. Nanocomposite films were fabricated by dispersing the CNCs and cationically modified CNCs (mCNCs) in CMC matrix through solution casting. The resultant CNC/CMC and mCNC/CMC films were then evaluated in terms of processability, mechanical properties and fracture surface morphology. Results showed that the reinforcing capacity of mCNCs was greatly dependent on its substitution degree. High substitution degree was favorable for obtaining mCNC/CMC film with uniform dispersion and superior mechanical properties. The observed distinctive reinforcing phenomena from CNCs and mCNCs in CMC matrix were interpreted in terms of dispersion state and interfacial bonding based on the fracture surface morphology. (C) 2016 Elsevier Ltd. All rights reserved.
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