期刊
CHEMSUSCHEM
卷 8, 期 5, 页码 894-900出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201403275
关键词
biomass; cleavage reactions; epr spectroscopy; polymerization; radicals
资金
- National Advanced Biofuel Consortium through National Renewable Energy Laboratory
- Office Of The Director
- EPSCoR [1101284] Funding Source: National Science Foundation
We report on the quantitative analysis of free radicals in bio-oils produced from pyrolysis of cellulose, organosolv lignin, and corn stover by EPR spectroscopy. Also, we investigated their potential role in condensed-phase polymerization. Bio-oils produced from lignin and cellulose show clear evidence of homolytic cleavage reactions during pyrolysis that produce free radicals. The concentration of free radicals in lignin bio-oil was 7.5x10(20)sping(-1), which was 375 and 138times higher than free-radical concentrations in bio-oil from cellulose and corn stover. Pyrolytic lignin had the highest concentration in free radicals, which could be a combination of carbon-centered (benzyl radicals) and oxygen-centered (phenoxy radicals) organic species because they are delocalized in a system. Free-radical concentrations did not change during accelerated aging tests despite increases in molecular weight of bio-oils, suggesting that free radicals in condensed bio-oils are stable.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据