期刊
CHEMSUSCHEM
卷 8, 期 17, 页码 2917-2926出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201500355
关键词
cobalt; graphene; hierarchical porous carbon; solvothermal; supercapacitors
资金
- National Nature Science Foundation of China [51402324, 51402325, 51302281]
- Innovative Research Fund of ICC-CAS [2012SCXQT03]
- Natural Science Foundation of Shanxi Province [2013011012-7]
- Innovative Research Fund of Taiyuan Science and Technology Bureau [2012CXJD0510]
- Shanxi Coal Transportation and Sales Group Co. Ltd [2013WT103]
Using graphene oxide and a cobalt salt as precursor, a three-dimensional graphene aerogel with embedded Co3O4 nanoparticles (3D Co3O4-RGO aerogel) is prepared by means of a solvothermal approach and subsequent freeze-drying and thermal reduction. The obtained 3D Co3O4-RGO aerogel has a high specific capacitance of 660 Fg(-1) at 0.5 Ag-1 and a high rate capability of 65.1% retention at 50 Ag-1 in a three-electrode system. Furthermore, the material is used as cathode to fabricate an asymmetric supercapacitor utilizing a hierarchical porous carbon (HPC) as anode and 6m KOH aqueous solution as electrolyte. In a voltage range of 0.0 to 1.5 V, the device exhibits a high energy density of 40.65 Whkg(-1) and a power density of 340 Wkg(-1) and shows a high cycling stability (92.92% capacitance retention after 2000 cycles). After charging for only 30 s, three CR2032 coin-type asymmetric supercapacitors in series can drive a light-emitting-diode (LED) bulb brightly for 30 min, which remains effective even after 1 h.
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