Highly Efficient Polymer-Supported Catalytic System for the Valorization of Carbon Dioxide

Polydibenzo-18-crown-6 was utilized as a co-catalyst and polymeric support in combination with potassium iodide for the synthesis of cyclic carbonates from carbon dioxide and epoxides under mild and solvent-free conditions. The efficiency of this catalytic system can be easily increased by loading the polymer with KI prior to the reaction. The influence of various reaction parameters were studied thoroughly. The scope and limitation of the catalyst system was studied at 80 degrees C and 100 degrees C. A large number of terminal epoxides (14) were converted to the desired cyclic carbonates in yields up to 99%. We could successfully recover and reuse the catalyst >20times with excellent yields up to 99%. Although, we observed that the activity gradually decreased after repetitive cycles. This decrease was attributed to KI leaching and partial degradation caused by mechanical stirring. This assumption is supported by scanning electron microscopy and energy dispersive X-ray spectroscopy.