期刊
CHEMPHYSCHEM
卷 16, 期 9, 页码 1996-2005出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201500095
关键词
dye-sensitized solar cells; organic electronics; phenothiazines; photoelectron spectroscopy; UV; Vis spectroscopy
Dithienylated phenothiazines (DTPTs) with different functional groups attached to the central nitrogen atom are presented as a class of versatile metal-free chromophores for the design of dye-sensitized solar cells (DSSCs) and organic light-emitting diodes (OLEDs). The electronic characteristics of spin-coated thin films on polycrystalline gold were studied using photoelectron spectroscopy assisted by theoretical calculations, scanning force microscopy, and UV/Vis spectroscopy. Complementary fluorescence spectra show light emission in the blue region (465 nm). The absorption properties and good hole-transporting abilities make DTPTs feasible hole-transporting materials (HTM) and metal-free chromophores in UV-sensitive solar cell designs.
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