期刊
CHEMPHYSCHEM
卷 16, 期 13, 页码 2755-2759出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201500448
关键词
density functional calculations; lithium-sulfur batteries; operando conditions; polysulfides; Raman spectroscopy
资金
- European Union Seventh Framework Programme [314515]
- Chalmers Areas of Advance Energy and Transport
Confocal Raman spectra of a lithium-sulfur battery electrolyte are recorded operando in a depth-of-discharge resolved manner for an electrochemical cell with a realistic electrolyte/sulfur loading ratio. The evolution of various possible polysulfides is unambiguously identified by combining Raman spectroscopy data with DFT simulations.
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