期刊
PHYSICAL REVIEW LETTERS
卷 116, 期 9, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.116.098301
关键词
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资金
- National Science Foundation [NSF DMR-1055586]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1055586] Funding Source: National Science Foundation
Periodic microphases universally emerge in systems for which short-range interparticle attraction is frustrated by long-range repulsion. The morphological richness of these phases makes them desirable material targets, but our relatively coarse understanding of even simple models hinders controlling their assembly. We report here the solution of the equilibrium phase behavior of a microscopic microphase former through specialized Monte Carlo simulations. The results for cluster crystal, cylindrical, double gyroid, and lamellar ordering qualitatively agree with a Landau-type free energy description and reveal the nontrivial interplay between cluster, gel, and microphase formation.
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