期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 18, 期 1, 页码 89-93出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cp05134g
关键词
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资金
- RFBR [14-03-00374-a, 14-03-31239-mol-a, 14-03-93183 MCXa]
- Russian Science Foundation [14-13-01053]
- Russian Science Foundation [14-13-01053] Funding Source: Russian Science Foundation
We demonstrate an analytical model for the description of the signal amplification by reversible exchange (SABRE) process. The model relies on a combined analysis of chemical kinetics and the evolution of the nuclear spin system during the hyperpolarization process. The presented model for the first time provides rationale for deciding which system parameters (i.e. J-couplings, relaxation rates, reaction rate constants) have to be optimized in order to achieve higher signal enhancement for a substrate of interest in SABRE experiments.
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