期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 18, 期 13, 页码 8920-8925出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cp00890a
关键词
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资金
- Fundacao para a Ciencia e Tecnologia (Portugal) - ERDF under the PT2020 Partnership Agreement [UID/QUI/50006/2013, POCI-01-0145-FEDER - 007265, SFRH/BPD/111168/2015]
- CNRS (France), Programme PHC PESSOA
- University of Bordeaux
- Ministere de la Recherche l'Enseignement Superieur
The introduction of two amine substituents in 4' and 7 positions, leads to the formation of a blue flavylium cation, 7-(N, N'-diethylamino)-2-(9-julolidine)-1-benzopyrilium, which is extremely stable across a wide acidic pH range. The kinetic and thermodynamic constants of the multistate system have been calculated by studying the relaxation kinetics after equilibrium perturbation by addition of base (direct pH jumps) or acid (reverse pH jumps). Except for the cis-chalcone, which is an elusive species, the relative energy levels of the other species could be calculated and a global energy level diagram constructed. The diagram explains that the stability of the diamino compound is due to the high energy level of the hemiketal species, which is difficult to access in acidic medium.
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