期刊
PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES
卷 79, 期 -, 页码 188-197出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.physe.2015.12.024
关键词
Intrinsic and extrinsic ZnO nanostructures; Crystallography; Morphology; Photoluminescence
资金
- University Grants Commission, New Delhi
- Leading Foreign Research Institute Recruitment Program through the National Research Foundation of Korea (NRF) - Ministry of Education, Science and Technology (MEST) [2014-039452]
Semiconductor nanostructures catch the attention due to morphology tunable properties. SPAN-80 Capped intrinsic and extrinsic ZnO nanostructures have been synthesized by the simple wet-chemical synthesis route. Structural behavior (morphology and crystallography) and photoluminescence performance of synthesized nanomaterials have been explored as a function of variable SPAN-80 concentration (0.05-0.125%). Crystallographic studies reveal that the prepared products possess wurtzite structure. Electron microscopy infers that the quantum dots are bunched together to form multifaceted morphology for 0.05% SPAN-80 concentration, whereas rectangular shape has been observed for extreme capping concentration. Photoluminescence properties have affected drastically with the introduction of SPAN-80 during the precipitation reaction. Photoluminescent properties of the synthesized nanostructures are strongly dependent on SPAN-80 concentration. Augmentation of capping concentration from 0.05% to 0.075% diminishes the luminescence quantum yield due to increased surface passivation whereas further addition of capping agent beyond the optimum capping concentration (0.075%) enhances the PL intensity due to increased energy transfer from capping shell to the nanostructure core. (C) 2015 Elsevier B.V. All rights reserved.
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