期刊
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
卷 191, 期 4, 页码 584-587出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426507.2015.1128911
关键词
Alumole; gallole; alumepin; 1-haloalumole
资金
- JSPS KAKENHI [24109013, 24550048, 2662028, 15H05477]
- MEXT Project of Integrated Research on Chemical Synthesis from the Ministry of Education, Culture, Sports, Science, and Technology (Japan)
- Molecular Systems Research project of the RIKEN Advanced Science Institute
- Collaborative Research Programof the Institute for Chemical Research, Kyoto University
- Grants-in-Aid for Scientific Research [24109013, 15H05477, 24550048] Funding Source: KAKEN
Stable alumole and gallole derivatives have been synthesized, and their reactivity was investigated. Mes(*)-substituted alumole and gallole have tri-coordinated heavier group 13 element moieties even in the presence of Lewis bases, because of the steric hindrance of the bulky Mes(*) group. Treatment of the Mes(*)-substituted heavier group 13heteroles with Li metal afforded the Li salts of the corresponding heterole dianions. Furthermore, 1-bromo- and 1-chloro-alumole derivatives were synthesized by applying the same synthetic method as used for the synthesis of the Mes(*)-substituted alumole. In the solid state, the 1-haloalumoles exhibit dimeric structures due to the halogen-aluminum coordination interactions. Utilization of the 1-bromoalumole for the synthesis of new cyclic organoaluminum compounds through the reactions with nucleophiles and alkynes are also described.
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