期刊
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
卷 192, 期 2, 页码 192-196出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426507.2016.1255616
关键词
Carboranes; metallacarboranes; sulfur derivatives
资金
- Russian Foundation of Basic Research [08-03-00463, 12-03-00772, 16-53-53079, 16-33-00607]
A series of new closo- and nido-carborane based thioethers with exo-polyhedral carbon-sulfur bond 1-X(CH2)(n)S-1,2-C2B10H11 (X = COOH, N-3, CH(NH2)COOH) and [7-X(CH2)(n)S-7,8-C2B9H11](-) (X = COOH, N-3, NH2, CH(NH2)COOH) was prepared by alkylation of 1-mercapto-1,2-carborane. Dialkylsulfonium derivatives of nido-carborane 9-R(Me)S-7,8-C2B9H11 and 10-R(Me)S-7,8-C2B9H11 with exo-polyhedral boron-sulfur bond were prepared by alkylation of the corresponding methyl-carboranyl thioether. Isomeric MeS derivatives of transition metal bis(dicarbollide) complexes [X,Y-(MeS)(2)-3,3'-M(1,2-C2B9H10)(2)](-) were prepared starting from the corresponding methylcarboranyl thioethers. [GRAPHICS] .
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