期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 29, 页码 10314-10317出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201501583
关键词
asymmetric catalysis; dearomatization; hypervalent iodine; organocatalysis; spirooxindoles
资金
- MOST (973 project) [2015CB856600]
- NSFC [21232007]
- Ministry of Education
The first enantioselective dearomatizative spirocyclization of 1-hydroxy-N-aryl-2-naphthamide derivatives has been accomplished by chiral organoiodine catalysis to stereoselectively create an all-carbon stereogenic center, providing a straightforward approach to access spirooxindole derivatives in good yields and with high to excellent levels of enantioselectivity. Chiral hypervalent phenyl-(3)-iodanes generated in situ from the oxidation of the chiral phenyl iodine actually participate in the asymmetric oxidative dearomatizative spirocyclization reaction.
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