期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 20, 页码 7332-7339出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201406318
关键词
carbenes; carbenoids; carbocations; Fischer carbenes; gold
资金
- MINECO (Severo Ochoa Excellence Accreditation) [SEV-2013-0319, CTQ2013-42106-P]
- European Research Council [321066]
- AGAUR [2014 SGR 818]
- ICIQ Foundation
- COFUND (Marie Curie program) postdoctoral fellowship
By reviewing the recent progress on the elucidation of the structure of gold carbenes and the definitions of metal carbenes and carbenoids, we recommend to use the term gold carbene to describe gold carbene-like intermediates, regardless of whether the carbene or carbocation extreme resonance dominates. Gold carbenes, because of the weak metal-to-carbene p-back-donation and their strongly electrophilic reactivity, could be classified into the broader family of Fischer carbenes, although their behavior and properties are very specific.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据