期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 38, 页码 13196-13200出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201502193
关键词
aggregation-induced emission; 1; 1-binaphthol; circular dichroism; circularly polarized luminescence; configuration inversion
资金
- National Natural Science Foundation of China [21174061, 51173078, 21172106, 21474048]
- open project of Beijing National Laboratory for Molecular Sciences
Four aggregation-induced emission (AIE)-active chiral binaphthyl-based molecules, (R/S)-1 and (R/S)-2, were designed and synthesized. Interestingly, all of them can exhibit reversal circularly polarized luminescence (CPL) signals from solution to aggregation, which could be attributed to the different dihedral angle of binaphthyl units from cis-conformation in pure THF solution to trans-conformation in THF/water mixtures.
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