期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 35, 页码 12271-12274出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201501239
关键词
aromaticity; cluster compounds; heterocycles; metal-metal bonds; metallacycles
资金
- CNRS
- UPMC
- MIUR
A simple synthetic method allows the one-pot assembly of C-3-symmetric, 44-core-valence-electron, triangular Pd or Pt clusters and their heterobimetallic mixed Pd/Pt analogues. These mixed metal complexes are the first examples of stable triangular all-metal heteroaromatics. In contrast to traditional heteroaromatic molecules formed combining main-group elements, they actually retain structural and electronic features of their homonuclear analogues.
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